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1 Formulas

  • The total electron-phonon coupling constant \lambda can be obtained by \lambda=\sum_{q\nu}\lambda_{q\nu}=2\int_0^{\omega}\frac{\alpha^2F(\omega)}{\omega}d\omega \lambda_{q\nu}=\frac{\gamma_{q\nu}}{\pi{h}N(E_f)\omega^2_{q\nu}} where Eliashberg spectral function is \alpha^{2}F(\omega)=\frac{1}{2\pi{N}(E_F)}\sum_{q\nu}\delta(\omega-\omega_{q\nu})\frac{\gamma_{q\nu}}{\hbar\omega_{q\nu}}

  • The cirtical temperatures T_c were estimated by Allan−Dynes-modified McMillan’s approximation of the Eliashberg equation[1,2],

T_c =\frac{\omega_{log}}{1.2}\exp[-\frac{1.04(1+\lambda)}{\lambda-\mu_c^*(1+0.62\lambda)}]

where \mu_c^* is effective screened Coulomb repulsion constant (typically \sim 0.1), \lambda is the overall electron−phonon coupling strength computed from the frequency-dependent Eliashberg spectral function and \omega_{log} is the properly defined logarithmic average frequency.

  • The logarithmically averaged characteristic phonon frequency \omega_{log} is defined as \omega_{log}=\exp(\frac{2}{\lambda}\int\frac{d\omega}{\omega}\alpha^2F(\omega)log\omega)
[1]
McMillan, W. L. Transition Temperature of Strong-Coupled Superconductors. Phys. Rev. 1968, 167, 331–344.
[2]
Allen, P. B.; Dynes, R. C. Transition Temperature of Strong-Coupled Superconductors Reanalyzed. Phys. Rev. B 1975, 12, 905–922.